Salts — Formulas and Industrial Uses hero

Salts — Formulas and Industrial Uses

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In 30 seconds
  • Definition: Salt = product of acid + base neutralisation. NaCl, KCl, CaSO₄ etc.
  • Common salts: NaCl (common salt), NaHCO₃ (baking soda), Na₂CO₃ (washing soda), CaOCl₂ (bleaching powder), CaSO₄·½H₂O (plaster of Paris).
  • Industrial: Chlor-alkali industry (NaOH, Cl₂, H₂ from brine). Cement uses gypsum.

Salts are everywhere — kitchen, laundry, hospital, construction. CDS/OTA tests common salt names, formulas and industrial preparations.

Types of Salts

  • Neutral salts: formed from strong acid + strong base. NaCl (HCl + NaOH).
  • Acidic salts: contain replaceable H. NaHSO₄, NaHCO₃ (mild base in solution).
  • Basic salts: contain OH or O. Cu(OH)Cl, basic copper carbonate (verdigris).
  • Hydrated salts: contain water of crystallisation. CuSO₄·5H₂O (blue vitriol), Na₂CO₃·10H₂O (washing soda).
  • Anhydrous salts: water removed on heating. Used as drying agents (e.g., anhydrous CaCl₂).

Important Salts

Common nameChemical name / formulaUse
Common saltSodium chloride NaClCooking, preservation, chlor-alkali raw material
Baking sodaSodium bicarbonate NaHCO₃Baking (releases CO₂), antacid, fire extinguishers
Washing sodaSodium carbonate Na₂CO₃·10H₂OGlass, soap, paper industries; softening hard water
Bleaching powderCalcium hypochlorite CaOCl₂Disinfection of water, bleaching of textile/paper
Plaster of ParisCalcium sulphate hemihydrate CaSO₄·½H₂OCasts for fractures, statues, decorative work
GypsumCaSO₄·2H₂OCement-setting retarder, fertiliser
Blue vitriolCuSO₄·5H₂OFungicide, electroplating
Green vitriolFeSO₄·7H₂OIron supplement, ink, dye
Epsom saltMgSO₄·7H₂OLaxative; bath salts

Chlor-Alkali Industry

  • Electrolysis of brine (concentrated NaCl solution):
  • At cathode: 2H₂O + 2e⁻ → H₂ + 2OH⁻ (H₂ released).
  • At anode: 2Cl⁻ → Cl₂ + 2e⁻ (Cl₂ released).
  • NaOH accumulates in solution.
  • Three useful products — NaOH (soaps, paper), Cl₂ (disinfection, PVC) and H₂ (fuel, ammonia synthesis).

CDS/OTA PYQ Examples

Q: Chemical formula of baking soda is:

(a) Na₂CO₃ (b) NaHCO₃ (c) NaOH (d) Na₂SO₄

Answer: (b) NaHCO₃.

Q: Plaster of Paris is:

(a) CaSO₄ (b) CaSO₄·½H₂O (c) CaSO₄·2H₂O (d) CaCO₃

Answer: (b) Calcium sulphate hemihydrate.

Q: Bleaching powder is:

(a) NaOCl (b) CaOCl₂ (c) Ca(OH)₂ (d) NaHCO₃

Answer: (b) Calcium hypochlorite, CaOCl₂.

Q: Washing soda contains how many water molecules of crystallisation?

(a) 2 (b) 5 (c) 7 (d) 10

Answer: (d) 10 — Na₂CO₃·10H₂O.

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Frequently Asked Questions

Why does baking soda make cakes rise?

On heating it releases CO₂ gas (2NaHCO₃ → Na₂CO₃ + H₂O + CO₂), leavening the dough.

Why is gypsum added to cement?

To retard setting — without it, cement sets too quickly to be useful for construction.

How does Plaster of Paris harden?

It absorbs water and re-forms gypsum: CaSO₄·½H₂O + 1½H₂O → CaSO₄·2H₂O. The process is fast and exothermic.